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Peculiarities of U-based Laves phases

Publication at Faculty of Mathematics and Physics |
2010

Abstract

This contribution focuses on the structural and physical properties of U-based Laves phases. The majority of the uranium Laves phases show a weakly paramagnetic behaviour.

The reason is the compact structure of the phases that leads to small a U-U spacing as well as very high coordination numbers, regarding both the uranium and the ligands sublattices, which brings a strong hybridization with non-f states. However, there are some exceptions of uranium Laves phases that do order magnetically (UFe2, UNi2 and the recently discovered U2Fe3Ge compound).