Abstract
The tin atom in solid state structures of {2-[(CH3)(2)NCH2]C6H4}nBu(2)SnCl (1) is five coordinated, with organic groups in the equatorial and chlorine and intramolecularly coordinated amino group in axial positions. The tin atom in {2-[(CH3)(2)NCH2]C6H4}nBuSnCl(2) (2) is six coordinated, interacting with the chlorine atom from the adjacent molecule.