Square planar diphosphinoazine rhodium(I) amido carbonyl complexes with an unsymmetrical PNP ' pincer-type coordination

Abstract

A series of novel diphosphinoazine rhodium amido carbonyl complexes was prepared by deprotonation of cationic diphosphinoazine rhodium complexes. The crystal structures of two cationic and one neutral deprotonated complex were determined.

Keywords

• polydentate ligands
• diphosphinoazines
• rhodium complexes
• carbonyl complexes
• pincer complexes