Lanthanide and actinide extractions with anionic ligands based on cobalt bis(dicarbollide) ions with covalently bonded CMPO functions

Abstract

Compounds were synthesized with the aim to develop efficient extraction agents for liquid-liquid extraction of polyvalent cations, i.e. lanthanides and actinides from high-level activity nuclear waste. Compounds of general formulation [(8-CMPO-(CH2-CH2O)

Keywords

• carboranes
• metallaboranes
• dicarbollides
• CMPO
• liquid-liquid extraction
• lanthanide
• actinide extraction
• boron-cluster compounds
• diglycolamide todga
• radioactive-wastes
• crystal-structures
• minor actinides
• nuclear-wastes
• separation
• chemistry
• radionuclides
• derivatives