Preparation, structural characterisation and electrochemical properties of iron(0) and tungsten(0) carbonyl complexes with 1-(diphenylphosphanyl)-1 '-vinylferrocene and 1-(diphenylphosphanyl)-1 '-(dimethylvinylsilyl)ferrocene as P-monodentate ligands

Abstract

Preparation, structural characterisation and electrochemical properties of iron(0) and tungsten(0) carbonyl complexes with 1-(diphenylphosphanyl)-1 '-vinylferrocene and 1-(diphenylphosphanyl)-1 '-(dimethylvinylsilyl)ferrocene as P-monodentate ligands

Keywords

• ferrocene
• alkenylphosphanes
• iron
• tungsten
• electrochemistry
• structure elucidation
• unsaturated tertiary phosphines
• catalyzed asymmetric 1,4-addition
• metal-complexes
• crystal-structure
• olefin complexes
• coordination chemistry
• molecular-structures
• arsines
• ferrocene
• ruthenium