Fluorosilyl-substituted cyclopentadienyltitanium(IV) complexes: Synthesis, structure, and styrene polymerization behavior

Abstract

The synthesis and characterization of new halo-silyl-substituted titanium(IV) derivatives [TiCl3(eta(5)-C5H4SiCl3)] (9), [TiCl3(eta(5)-C5H4SiMe2F)] (10), [TiCl3(eta(5)-C5H4SiMeF2)] (11), [TiCl3(eta(5)-C5H4SiF3)] (12), and [TiF3(eta(5)-C5H4SiMe2F)] (13) a

Keywords

• half-sandwich complexes
• ti-47
• ti-49 nmr-spectra
• titanium complexes
• syndiotactic polystyrene
• crystal-structures
• catalysts
• derivatives
• zirconium
• chloro
• reactivity