Formation and dissociation kinetics of Eu(III) complexes with H(5)do3ap and similar dota-like ligands

Abstract

Formation and dissociation kinetics of Eu(III) complexes of H4dota and their analogues containing phosphonic or phosphinic acid moiety were studied by time-resolved laser-induced fluorescence spectroscopy (TRLIFS).

Keywords

• macrocyclic ligands
• cyclen derivatives
• phosphinate and phosphonate complexes
• europium(III) complexes
• thermodynamics and kinetics
• molecular spectroscopy
• time-resolved laser-induced fluorescence spectroscopy (TRLIFS)
• luminescence probes