Kinetic study of dissociation of Eu(III) complex with H(8)dotp (H(8)dotp=1,4,7,10-tetraazacyclododecane-1,4,7,10-tetrakis(methylphosphonic acid))

Abstract

Dissociation kinetics of the Eu-dotp complex was studied by UV and luminescence spectroscopies. Time-resolved laser-induced fluorescence spectroscopy (TRLIFS) was utilized to deduce composition of reaction intermediates and final products.

Keywords

• macrocyclic complexes
• cyclen derivatives
• phosphonate complex
• Europium(III) complex
• dissociation kinetics
• molecular absorption spectroscopy
• time-resolved laser-induced fluorescence spectroscopy (TRLIFS)