Vanadocene(IV) dicyanide complexes: the evidence super-hyperfine coupling for compounds with (CN)-C-13 ligands

Abstract

An EPR study of the vanadocene complexes (C5H5)(2)V(CN)(2) and (CH3C5H4)(2)V(CN)(2) was carried out. Such compounds show strong super-hyperfine coupling (vertical bar a(iso)(C-13)vertical bar similar to 1.27 mT) when C-13 labeled cyanide is used for thei

Keywords

• bent metallocene
• pseudolialide complexes
• EPR spectroscopy
• super-hyperfine coupling
• X-ray structure
• x-ray-diffraction
• acid complexes
• vanadium(iv)
• dichloride