Double O,C,O-chelated diorganotin(IV) derivatives

Abstract

Novel diorganotin(IV) compounds (L-1,L-2)(2)SnCl2 where L-1,L-2 are O,C,O-chelating ligands (called the pincer ligands), 2,6-bis(alkoxy-methyl)phenyl-, 2,6-(ROCH2)(2)C6H3-. (L-1, R =Me, L-2, R = t-Bu), have been synthesized and characterized by H-1, C-13

Keywords

• tin
• NMR
• chelating ligand
• X-ray structure
• alcohol acetylation catalysts
• ray structural-analysis
• crystal-structure
• solid-state
• organotin compounds
• molecular-structure
• carboxylic-acids
• pi-coordination
• polysulfonylamines
• cations