Cleavage of the epimines of 1,6-anhydrohexoses with fluoride anion.

Abstract

Aziridine ring cleavage reactions of five N-nosylepimines having D-talo, D-galacto, D-manno, and D-allo configurations with potassium hydrogendifluoride under various reaction conditions have been performed.

Keywords

• cleavage reactions
• fluorine
• NMR spectroscopy
• aziridines
• aminosugars
• anhydrosugars
• fluorosugars
• carbohydrates