Homogenous and Hybrid Catalysts for Phenylacetylene Polymerization Formed by Ligand Exchange Activation of Rh-comlexes with Cyclooctatetraene.

Abstract

[Rh(CH2=CH2)2acac], [Rh(CH2=CH2)2Cl]2, [Rh(1,5-hexadiene)2Cl]2 Complexes and Hybrid System [Rh(1,5-hexadiene)2Cl]2 /PBI which are Catalyticaly Non-active were Activated by Ligand Exchange with Cyclooctatetraene into Highly Active Polym. Catalysts

Keywords

• phenylacetylene
• polymerization
• Rh-complexes
• hybrid catalysts
• cyclooctatetraene
• ligand exchange