Thermolysis of iron N-allylaminocarbene complexes: Formation of eta(3)-1-azaallylirontricarbonyl complexes. Synthetic and theoretical study

Abstrakt

Both chelated and nonchelated N-allyl-N-methylaminocarbene complexes of iron unsubstituted at the 1- and 3-positions of an allyl substituent afforded by thermolysis new eta(3)-iron tricarbonyl complexes of 2,3-dihydropyrrole.

Klíčová slova

• Císařová Ivana, l. 1249 ALKENE AMINOCARBENE COMPLEXES
• X-RAY STRUCTURE
• (AMINOCARBENE)CHROMIUM(0) COMPLEXES
• DIMETHYL ACETYLENEDICARBOXYLATE
• 1,3-DIPOLAR CYCLOADDITION
• DOUBLE-BOND
• REACTIVITY
• CHROMIUM
• ALKYNES
• CYCLOPROPANATION