Metal-promoted cage rearrangements in the tricarbollide series: Conversion of ligand derivatives 7-L-nido-7,8,9-C3B8H10 (L=H3N, tBuH(2)N, Me2HN) into neutral 8-R-nido-7,8,9-C3B8H11 (R=H2N, tBuHN, Me2N) compounds

Abstrakt

Metal-promoted cage rearrangements in the tricarbollide series: Conversion of ligand derivatives 7-L-nido-7,8,9-C3B8H10 (L=H3N, tBuH(2)N, Me2HN) into neutral 8-R-nido-7,8,9-C3B8H11 (R=H2N, tBuHN, Me2N) compounds

Klíčová slova

• Císařová
• Ivana tel: [phone] boranes
• carboranes
• NMR spectroscopy
• rearrangement
• N ligands