Synthesis and crystal structures of .mu-1,3-bis(η(5)-tetramethylcyclopentadienyl)-1,1,3,3-etramethyldisiloxane)[η(2 )-bis(trimethylsilyl)ethyne]titanium(II) and a doubly tucked-in product of its thermolysis

Abstract

Synthesis and crystal structures of .mu-1,3-bis(η(5)-tetramethylcyclopentadienyl)-1,1,3,3-etramethyldisiloxane)[η(2 )-bis(trimethylsilyl)ethyne]titanium(II) and a doubly tucked-in product of its thermolysis

Keywords

• Titanium
• ansa-Titanocene complexes
• Siloxane bridge
• Thermolysis
• Allyldiene ligand
• Crystal structures