Thermolysis of iron N-allylaminocarbene complexes: Formation of eta(3)-1-azaallylirontricarbonyl complexes. Synthetic and theoretical study

Abstract

Both chelated and nonchelated N-allyl-N-methylaminocarbene complexes of iron unsubstituted at the 1- and 3-positions of an allyl substituent afforded by thermolysis new eta(3)-iron tricarbonyl complexes of 2,3-dihydropyrrole.