Palladium(II) Complexes of 2-Dimethylamino-2'-diphenylphosphino-1,1'-binaphtyl (MAP) with Unique P,C-Coordination and Their Catalytic Activity in Allylic Substitution, Harwig-Buchwald Amination, and Suzuki Coupling

Abstract

The NMR and X-ray structural characterization of unusual Pd(II) complexes proved as P, C chelates, which have to be considered as a potentional binding mode in their reactions.