A Series of the Twelve-Vertex Ferratricarbollides [2-(C5H5)-9-X-closo-2,1,7,9-FeC3B8H10] (Where X= H2N, MeHN, BuHN, Bu(Me)N. A Highly Stable Metallatricarbaborane System with Amine Functions in the Para Position to the Metal Center.
Publication at First Faculty of Medicine, Faculty of Mathematics and Physics |
The procedure leading to rearrangement complexation of amine tricarbollides is reported, leading to a series of new isomers. The products are characterized by NMR and X-ray.