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Three-electron collective Auger decay in CH3F

Publication at Faculty of Mathematics and Physics |
2015

Abstract

We report on experimental and theoretical study of collective Auger decay of double inner-valence vacancy in fluoromethane, in which two electrons simultaneously fill the vacancies and a third electron is ejected to continuum. Calculations predict the respective lifetime of the double vacancy state to be in the femtosecond range, typical for two-electron Auger decay.

Measured electron spectra indirectly support this rather surprising result.