Crystal structure of chlorido{[3-(eta(5)-cyclopenta-dienyl)-2,2,3-trimethyl-1-phenylbutyliden e]azanido-kappa N}[eta(2)(N,O)-N,N-dimethylhydroxyl-aminato]titanium(IV), C20H27ClN2OTi

Abstract

C20H27ClN2OTi, monoclinic, P21/c (no. 14), a= 9.4006(2) angstrom, b= 10.8185(3) angstrom, c= 19.4821(5) angstrom, beta= 97.941(1)degrees, V = 1962.34(9) angstrom(3), Z = 4, R-gt(F)= 0.0270, wR(ref)(F-2)= 0.0731, T = 150(2) K.

Keywords

• group-4 metal-complexes
• hydroxylaminato complexes
• cyclopentadienyl
• transformations
• polymerization
• propylene
• ligands