Publication at Faculty of Physical Education and Sport |
2016
Abstract
On-line hyphenation of a home-made electrochemical cell with an electrospray ionization mass spectrometer (EC-ESI-MS) was investigated to be applicable in mimicking of thiram (T) meabolism. The EC-ESI-MS instrumental approach confirms the creation of the first metabolic product of T(Tm).
Tm is created via the decay of the disulfide bond. The catalytic effect of copper orginated from the copper working electrode to this reaction is discussed.