Abstrakt
Triazoles are agrochemicals or pharmaceuticals used for protection of crop or skin against fungi or mildew. The mechanism of their action lies in the inhibition of sterols biosynthesis.
It is known that essential metals significantly influence the behaviour of azoles in the manner of (i) complexes creation with them, (ii) changes of redox behaviour and (iii) degradation pathways. It is not clear how the cocktail effect of other present biological active chemicals modify the inhibitory effect of azoles (penconazole) to aromatase.
We provide the experiments in the gas phase to clarify the reaction mechanisms modifications as an effect of essential metals presence.