Abstrakt
Iron-rich rare-earth compounds are the basis for high-energy permanent magnets. These include the R(Fe,T)(12), R2Fe17, and R2Fe14B intermetallics (R rare earth; T Ti, V, Mo, Si) that readily absorb hydrogen, which changes their fundamental and functional characteristics.
In this letter, we investigate the stability of the magnetic properties of some hydrides with maximum hydrogen content (namely, TmFe11TiH1 and Tm2Fe17H5.5) in a wide temperature range using high magnetic fields. The magnetic phase transition from the ferrimagnetic to the ferromagnetic state was studied immediately after hydrides were obtained, as well as after one year of storage of the samples at ambient temperature.
Only the TmFe11TiH hydride is stable over time. The effect of hydrogen on the magnetothermal properties of the Nd2Fe14B and Nd1Pr1Fe14B compounds and a range of magnetic phase transitions were also investigated.
Hydrogenation leads to a decrease in the magnetocaloric effect in all investigated compounds as a result of an increase in the distance between magnetically active ions due to the lattice expansion. A magnetic phase diagram is constructed.