We provide a new value for the ratio R = Gamma(pi(0) -> e(+)e(-)gamma(gamma))/Gamma(pi(0) -> gamma gamma) = 11.978(6) x 10(-3), which is by 2 orders of magnitude more precise than the current Particle Data Group average. It is obtained using the complete set of the next-to-leading-order radiative corrections in the QED sector, and incorporates up-to-date values of the pi(0)-transition-form-factor slope.
The ratio R translates into the branching ratios of the two main pi(0) decay modes: B(pi(0) -> gamma gamma) = 98.8131(6)% and B(pi(0) -> e(+)e(-)gamma(gamma)) = 1.1836(6)%.