Abstrakt
Intermolecular hydrogen bonds impede long-range (anti-)ferroelectric order of water. We confine H2O molecules in nanosized cages formed by ions of a dielectric crystal.
Arranging them in channels at a distance of similar to 5 angstrom with an interchannel separation of similar to 10 angstrom prevents the formation of hydrogen networks while electric dipole-dipole interactions remain effective. Here, we present measurements of the temperature-dependent dielectric permittivity, pyrocurrent, electric polarization and specific heat that indicate an order-disorder ferroelectric phase transition at T-0 approximate to 3 K in the water dipolar lattice.
Ab initio molecular dynamics and classical Monte Carlo simulations reveal that at low temperatures the water molecules form ferroelectric domains in the ab-plane that order antiferroelectrically along the channel direction. This way we achieve the long-standing goal of arranging water molecules in polar order.
This is not only of high relevance in various natural systems but might open an avenue towards future applications in biocompatible nanoelectronics.