Temperature versus composition phase diagram and temperature evolution of structure and modulation of Ni2MnGa1-xInx single crystals
Abstrakt
A series of single crystal Ni2MnGa1-xInx samples, varying in compositions between x = 0 to 0.15, were grown by Bridgman method. Critical temperatures were obtained from the magnetisation and electrical resistivity measurements.
A Curie temperature and the temperatures of pre-martensitic and martensitic transformation decrease with increasing indium content. The decrease rate is faster than the rate published previously on polycrystalline samples, since no martensitic transformation was observed in our samples with the indium content x > 0.05.
The results of X-ray diffraction measurements of low temperature martensitic phase show significant decrease of monoclinic lattice parameter alpha and increase of monoclinic lattice parameter c and gamma angle with respect to increasing indium content. Composition dependence was observed also for the modulation vector in martensitic and pre-martensitic phase, where its x and y coordinates gain values around 3/7 and 1/3 respectively. (C) 2020 Elsevier B.V.
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