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Synthesis, crystal structures and electrochemistry of ferrocenyl-substituted 1,3,4-oxadiazoles

Publication at Faculty of Science |
2010

Abstract

Ferrocenyl-substituted 1,3,4-oxadiazoles, 2-ferrocenyl-1,3,4-oxadiazole (1) and 2,5-diferrocenyl-1,3,4-oxadiazole (2), have been prepared from the corresponding hydrazides, (ferrocenecarbonyl)hydrazine (3) and 1,2-bis(ferrocenecarbonyl)hydrazine (4), and characterized by conventional spectroscopic methods (IR, NMR, MS) and elemental analyses. The solid-state structures of 1, 2 and 4 have been determined by single-crystal X-ray diffraction analysis.

Electrochemical properties of compounds 1 and 2 were further studied by voltammetric techniques.